1007346-00-0Relevant academic research and scientific papers
Base-catalyzed reactions enhanced by solid acids: Amine-catalyzed nitroaldol (Henry) reactions enhanced by silica gel or mesoporous silica SBA-15
Tanemura, Kiyoshi,Suzuki, Tsuneo
, p. 392 - 396 (2018)
The reactions of various aldehydes with CH3NO2 catalyzed by Et3N, n-C6H13NH2, and Me2N(CH2)2NH2 were accelerated by the addition of silica gel to give aromatic (aliphatic) β-nitroalcohols, aromatic nitroalkenes, and aromatic 1,3-dinitroalkanes, respectively. Mesoporous silica SBA-15 showed higher activity than silica gel for the synthesis of aromatic nitroalkenes by the reactions of the corresponding aldehydes with CH3NO2 catalyzed by n-C6H13NH2.
One-pot synthesis of 1 ,3-dinitroalkanes catalysed by nickel species
Gao, Min,Wei, Yu-Ping
, p. 146 - 148 (2013/07/05)
The reaction of aromatic aldehydes with nitromethane afforded a one-pot preparation of 1,3-dinitroalkanes in the presence of a nickel catalytic system. This efficient and simple method proceeded with moderate to high yields (56-99%) under mild conditions.
