1007361-33-2Relevant academic research and scientific papers
Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: Modeling copper-monooxygenase C-H hydroxylation
Maiti, Debabrata,Lee, Dong-Heon,Gaoutchenova, Katya,Wuertele, Christian,Holthausen, Max C.,Narducci Sarjeant, Amy A.,Sundermeyer, Joerg,Schindler, Siegfried,Karlin, Kenneth D.
, p. 82 - 85 (2008)
(Chemical Equation Presented) Donor makes the difference: The mononuclear η1-superoxo copper(II) complex 1 undergoes dioxygen activation with the addition of hydrogen-atom donors. Net O2-derived O-atom insertion into the N-methyl group of the ligand leads to formation of a copper(II)-alkoxide product 2. The cupric superoxo species 1 itself is not capable of the observed hydroxylation reaction.
