1007392-17-7Relevant academic research and scientific papers
Enantioselective rhodium-catalyzed conjugate alkynylation of 5-benzylidene Meldrum's acids with TMS-acetylene
Fillion, Eric,Zorzitto, Alexander K.
supporting information; experimental part, p. 14608 - 14609 (2010/01/06)
(Chemical Equation Presented) The enantioselective alkynylation of benzylidene Meldrum's acids has been successfully achieved through rhodium-catalyzed addition of TMS-acetylene in the presence of bisphosphine ligand 3,5-Xylyl-MeOBIPHEP. The resulting Mel
Sequential Rh(l)/Pd-catalyzed 1,4-addition/Lntramolecular allylation: Stereocontrolled construction of γ-butyrolactones and cyclopropanes
Fillion, Eric,Carret, Sebastien,Mercier, Lauren G.,Trepanier, Vincent E.
, p. 437 - 440 (2008/09/19)
The rhodium-catalyzed conjugate addition of functionalized vinyltin reagents to alkylidene Meldrum's acids, followed by Pd-catalyzed intramolecular allylation, is a direct entry into vinyl-substituted y-lactones via Oalkylation and vinylcyclopropanes via
