100741-37-5Relevant academic research and scientific papers
GEOMETRICAL LIMITATIONS IN THE INTRAMOLECULAR ADDITION OF UNSYMMETRICAL ALLYLSILANES TO ENONES
Majetich, Georg,Hull, Ken,Defauw, Jean,Shawe, Thomas
, p. 2755 - 2758 (2007/10/02)
The geometrical constraints of the fluoride-initiated and Lewis acid-catalyzed intramolecular addition of allylsilanes to enone systems were shown to be governed by kinetic-ring-size preferences.Molecules containing adjacent quaternary carbon atoms can be prepared using this method.
