100741-78-4Relevant academic research and scientific papers
Intramolecular Additions of Allylsilanes to Conjugated Dienones. The Synthesis of Three Perforanes
Majetich, George,Defauw, Jean,Ringold, Clay
, p. 50 - 68 (2007/10/02)
Intramolecular addition of allylsilanes to 3-vinylcycloalkenones provides a powerful means of constructing functionalized 5-5, 5-7, 6-5, and 6-7 bicyclic ring systems.Our results reveal a divergence in reactivity, dependent on reaction catalyst and substr
REGIOSELECTIVITY IN INTRAMOLECULAR ADDITION OF ALLYLSILANES TO CONJUGAT DIENONES
Majetich,G,Hull,K,Defauw,J,Desmond,R
, p. 2747 - 2750 (2007/10/02)
The intramolecular addition of allylsilanes to conjugated dienones shows a divergence of regioselectivity as a function of reagent and substrate structure.The creation of 5-5, 6-5, 5-7, and 6-7 bicyclic ring systems is reported.
