100758-71-2Relevant academic research and scientific papers
Remarkably stable tetrahedral intermediates: Carbinols from nucleophilic additions to N-acylpyrroles
Evans, David A.,Borg, George,Scheidt, Karl A.
, p. 3188 - 3191 (2007/10/03)
Sufficiently stable intermediates formed in the reaction of N-acylpyrroles (1) with hydride and Grignard reagents can undergo further synthetic transformations and chromatographic purification to enable the generation of pyrrolecarbinols 2 in 76-95% yields [Eq. (1)].
Stereocontrolled Synthesis of all Four Stereoisomers of Verrucarinolactone from (R)-2,3-O-isopropylideneglyceraldehyde
Mulzer, Johann,Salimi, Nabiollah
, p. 1172 - 1178 (2007/10/02)
A practical synthesis of (+)- and (-)-verrucarinolactone (2) and epiverrucarinolactone (1) from (R)-2,3-O-isopropylideneglyceraldehyde via the key intermediates 3a/b is described.
