1007587-55-4Relevant academic research and scientific papers
Fine-tunable tris(triazolyl)methane ligands for copper(I)-catalyzed azide-alkyne cycloaddition reactions
Ozkal, Erhan,Llanes, Patricia,Bravo, Fernando,Ferrali, Alessandro,Pericas, Miquel A.
, p. 857 - 869 (2014/04/03)
The preparation of a small library of modular tris(triazolyl)methane ligands for copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions is reported. The synthesis of the first generation ligand, tris(1-benzyl-1H-1,2,3- triazol-4-yl)methanol (1a), s
TRIS(1,2,3-TRIAZOL-4-YL)METHANE ORGANOMETALLIC COMPOUNDS AS CATALYSTS AND PROCESSES USING THEM.
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Page/Page column 40, (2011/02/24)
Compounds of formula (I) or theirs salts, where Y is a (C1-C4)alkyl biradical and n is 1 or 0; M is Cu, Ag, Au, V, Fe, Zn, Ni, Co, Mn, Ru, or Cr; R1 is a known ring system with 1 -2 rings, isolated or fused; each ring havi
A highly active catalyst for huisgen 1, 3-dipolar cycloadditions based on the tris(triazolyl)methanol-Cu(I) structure
Oezcubukcu, Salih,Ozkal, Erhan,Jimeno, Cirll,Pericas, Miquel A.
supporting information; experimental part, p. 4680 - 4683 (2009/12/09)
A new trls(1 -benzyl-1H-1, 2, 3-triazol-4-yl)methanol ligand 3 has been prepared by a triple Cu(l)-catalyzed alkyne-azilde 1,3-dipolar cycloaddition (CuAAC). Ligand 3 forms a stable complex with CuCl, which catalyzes the Huisgen 1,3-dipolar cycloaddition
Click-connected ligand scaffolds: macrocyclic chelates for asymmetric hydrogenation
Qing, Zhang,Takacs, James M.
, p. 545 - 548 (2008/09/17)
Click chemistry is used to construct ligand scaffolds for a series of chiral diphosphites. Enantioselectivity as high as 97% ee is obtained using these click ligands in rhodium-catalyzed asymmetric hydrogenation. Control experiments and spectroscopic data suggest that a 16-membered P,P-macrocyclic Rh(1) chelate is formed.
