1007602-98-3Relevant academic research and scientific papers
Efficient synthesis of transition-metal phthalocyanines in functional ionic liquids
Chauhan,Kumari, Pratibha,Agarwal, Shweta
, p. 3713 - 3721 (2008/09/19)
The synthesis of transition-metal phthalocyanines by the reaction of substituted and unsubstituted phthalonitriles in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and metal salts in functional imidazolium, pyridinium and ammonium ionic liquids at 100-140°C, is reported. The best yields of metallated phthalocyanines were achieved in butyl(2-hydroxyethyl)dimethylammonium bromide ionic liquid. Metallation of free-base phthalocyanines with different metal salts in the above ionic liquid has also been achieved in good yields. Georg Thieme Verlag Stuttgart.
