1007605-45-9Relevant academic research and scientific papers
Relay redox and Lewis acid catalysis in the titanocene- catalyzed multicomponent assembly of 1,5-enynes
Lepore, Antonio J.,Pinkerton, David M.,Ashfeld, Brandon L.
supporting information, p. 1500 - 1504 (2013/06/27)
Herein we describe a direct, multicomponent assembly of 1,5-enynes. The titanocene-catalyzed coupling of an aryl aldehyde, iodoalkyne, and allylsilane enables the convergent and rapid synthesis of this versatile architectural motif in good to excellent yields. Copyright
Gold(III)-catalyzed direct nucleophilic substitution of propargylic alcohols
Georgy, Marie,Boucard, Valérie,Debleds, Olivier,Zotto, Christophe Dal,Campagne, Jean-Marc
experimental part, p. 1758 - 1766 (2009/06/28)
Gold-catalyzed nucleophilic substitution of propargylic alcohols with various nucleophiles (allylsilane, electron-rich aromatics, alcohols, thiols, hydrides, 1,3-dicarbonyl derivatives, sulfonamides) is described under very mild conditions (room temperatu
