100779-93-9Relevant academic research and scientific papers
Intramolecular Formal oxa-[3 + 3] Cycloaddition Approach to the ABD System of Phomactin A
Cole, Kevin P.,Hsung, Richard P.
, p. 4843 - 4846 (2007/10/03)
(Equation Presented) The ABD-ring of phomactin A was synthesized using an intramolecular formal oxa-[3 + 3] cycloaddion of an α,β-unsaturated iminium salt tethered to a 1,3-diketone. This represents the first time that the 12-membered ring has been formed
STEREOSELECTIVE CYCLIZATION OF (E)- AND (Z)-5,6-DIMETHYL-8-TRIMETHYLSILYL-6-OCTENALS
Asao, Kazuhiko,Iio, Hideo,Tokoroyama, Takashi
, p. 6397 - 6400 (2007/10/02)
The diastereoselectivities in the acid-mediated cyclization of (E)- and (Z)-5,6-dimethyl-8-trimethylsilyl-6-octenals, both stereoselectively synthesized, were investigated.Excellent preference for the formation of cis-dimethylcyclohexanols was realized, s
