100780-35-6Relevant academic research and scientific papers
New strategy to construct fused/bridged/spiro carbocyclic scaffolds based on the design of novel 6-C synthon precursor
Liu, Jia,Wang, Xi,Sun, Chang-Liang,Li, Bi-Jie,Shi, Zhang-Jie,Wang, Min
supporting information; experimental part, p. 1572 - 1577 (2011/04/23)
In this article we report a new strategy to build fused/spiro/bridged carbocyclic systems with a novel 6-C synthon from readily available diallyl diacetates through the sequential Pd-catalyzed double allyl alkylation and Diels-Alder annulation. Further ex
RHODIUM (1) CATALYSED REGIOSPECIFIC CYCLISATION OF 1,6-ENYNES TO METHYLENECYCLOHEX-2-ENES
Grigg, Ronald,Stevenson, Paul,Worakun, Tanachat
, p. 4967 - 4972 (2007/10/02)
1,6-Enynes are cyclised regiospecifically by 5 mol percent of Wilkinson's catalyst in acetonitrile at 80 deg C to give the corresponding methylenecyclohex-2-enes usually in goog yield (62-83percent).Terminal substitution on either the alkene
Addition-Cyclization catalysed by Palladium(II)
Trost, Barry M.,Burgess, Kevin
, p. 1084 - 1086 (2007/10/02)
Palladium catalysed nucleophilic additions to 1,6-dienes and a 1,6-enyne lead to cyclization in preference to β-hydrogen insertion; a novel cyclization of a 1,6-enyne to a 1,2-dimethylenecyclopentane is also reported.
