100812-96-2

Upstream product

• 62952-33-4 3-ethoxy-6-methylcyclohex-2-en-1-one 
• 80121-73-9 2-(trimethylsilyl)methylallyl iodide 

Downstream Products

• 111470-39-4 4-methyl-4-<2-<(trimethylsilyl)methyl>allyl>-3-cyclohexenyl-2-cyclohexen-1-one 
• 87603-69-8 4-methyl-4-<2-allyl>-2-cyclohexen-1-one 
• 111470-80-5 4-Methyl-4-(2-methyl-allyl)-3-(2-methyl-propenyl)-cyclohex-2-enone 
• 100812-56-4 3,4-dimethyl-4-<2-<(trimethylsilyl)methyl>allyl>-2-cyclohexen-1-one 
• 100812-59-7 3,4-dimethyl-4-(2-methyl-propenyl)-2-cyclohexen-1-one 
• 100812-44-0 4-methyl-4-(2-methyl-2-propenyl)-2-cyclohexen-1-one 
• 100741-77-3 4-methyl-4-<2-<(trimethylsilyl)methyl>allyl>-3-vinyl-2-cyclohexen-1-one 
• 111470-38-3 4-methyl-4-<2-<(trimethylsilyl)methyl>allyl>-3-(2-propenyl)-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Allylsilane-Initiated Cyclopentane Annulations

The utility of intramolecular allylsilane additions to various Michael acceptors for achieving cyclopentane annulation is reported.Our results revealed that fluoride ion catalysis annulated both acyclic and cyclic systems, while Lewis acid catalyses (TiCl

ALLYLSILANE INITIATED CARBOCYCLIZATIONS

The intramolecular conjugate addition of an allylic anion, generated from a allylsilane moiety, with various Michael acceptors is reported.