100820-83-5Relevant academic research and scientific papers
The efficient enantiodivergence of (dl)-1,3-diacetyl-2- imidazolidinethiones by enantioselective catalytic deacetylation
Yokoyama, Kazuhiro,Ishizuka, Tadao,Kunieda, Takehisa
, p. 6285 - 6288 (1999)
An enantioselective borane-mediated deacylation of C2- symmetrical 1,3- diacetyl-2-imidazolidinethiones, catalyzed by oxazaborolidines derived in situ from an aminoalcohol 2 and borane, provides a promising process for highly effective kinetic
REACTIONS WITH 4,5-DIPHENYLIMIDAZOLIDINE-2-THIONE, II
Hammouda, Hamdy Ali,Abd-Allah, Sanaa Osman,Zoorob, Hanafi Hassan
, p. 49 - 56 (2007/10/02)
4,5-diphenylimidazolidine-2-thione (I) added acrylonitrile to give the N-cyanoethyl derivative, II.Hydrolysis of II by alkali gave the carboxyethyl derivative, V, while by acids the imidazo-thiazine derivative, IV was obtained.Compound I gave also N-Mannich bases, VIII.Dehydrogenation of I and desulfurization by various methods were investigated.Oxidation of the S-alkyl and S-aryl derivatives to a sulfoxide, XIV and to sulfones, XV were also tried.
