100835-59-4

Basic information

• Product Name: 4-BroMoanisole-d3
• Synonyms: 4-BroMoanisole-d3;1-bromo-4-(trideuteriomethoxy)benzene
• CAS NO: 100835-59-4
• Molecular Formula: C₇H₇BrO
• Molecular Weight: 190.052365334
• Mol File: 100835-59-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-BroMoanisole-d3(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BroMoanisole-d3(100835-59-4)
• EPA Substance Registry System: 4-BroMoanisole-d3(100835-59-4)

Safety Data

• Hazardous Substances Data: 100835-59-4(Hazardous Substances Data)

Usage

Description

4-Bromoanisole-d3, also known as p-Methoxyphenyl Bromide-d3 (M265815), is a deuterated compound commonly utilized in the field of chemistry and materials science. It is characterized by the presence of deuterium (D), an isotope of hydrogen, which provides unique properties for various applications.

Uses

Used in Semiconductor Industry:
4-Bromoanisole-d3 is used as a solvent additive for controlling the morphology and crystallization in semiconducting polymer blends. Its deuterated nature allows for enhanced control over the polymer's properties, leading to improved performance in electronic devices.
Used in Chemical Research:
In the field of chemical research, 4-Bromoanisole-d3 serves as a valuable compound for studying reaction mechanisms and understanding the behavior of molecules. The presence of deuterium in the molecule can provide insights into the kinetics and thermodynamics of chemical reactions, making it a useful tool for researchers.
Used in Material Science:
4-Bromoanisole-d3 is also employed in material science as a component in the development of novel materials with specific properties. Its deuterated nature can contribute to the enhancement of material characteristics, such as stability, solubility, and reactivity, which can be beneficial in various applications.

Upstream product

• 6552-74-5 potassium deuterated methoxide 
• 6324-15-8 toluene-4-sulfonic acid 4-bromo-phenyl ester 
• 106-41-2 4-bromo-phenol 
• 23726-00-3 <²H9>trimethylsulphoxonium iodide 

Downstream Products

• 100835-60-7 1,1-bis-(p-<²H3>methoxyphenyl)ethene 

Relevant articles and documents

Preparation method of nitrogen-alkyl (deuterated alkyl) aromatic heterocycle and alkyl (deuterated alkyl) aryl ether compound

The invention provides a method for preparing nitrogen-alkyl(deuterated alkyl)aromatic heterocycle and alkyl(deuterated alkyl)aryl ether compounds. The method adopted in the invention specifically comprises the following steps: firstly, adding an alkoxy base (MOR') or a combination reagent Q (comprising a base M'X, an alcohol C and a molecular sieve E) into a solvent B to be stirred; then, addingan aromatic compound D of nitrogen sulfonyl or oxygen sulfonyl into a mixture; separating and purifying after reaction to obtain nitrogen-alkyl(deuterated alkyl)aromatic heterocycle or alkyl(deuterated alkyl)aryl ether. The method can realize one-step conversion from an electron withdrawing benzenesulfonyl protecting group on a nitrogen or oxygen atom to an electron donating alkyl protecting group, avoids using highly toxic alkyl halide, and has advantages of being efficient, economical, environmentally friendly, mild in condition, good in substrate universality and high in yield; the prepareddeuterated compounds can be widely applied to the fields of pharmaceutical chemistry and organic chemistry synthesis.

Trideuteromethylation Enabled by a Sulfoxonium Metathesis Reaction

A conceptually novel sulfoxonium metathesis reaction between TMSOI and cost-effective DMSO-d6 is developed for the efficient generation of a new trideuteromethylation reagent TDMSOI. The new reagent TDMSOI is produced highly efficiently by simply heating a mixture of TMSOI and DMSO-d6 and directly used for subsequent trideuteromethylation in a "one-pot" operation. The preparative power of the new versatile reagent and the "one-pot" protocol is demonstrated by its use to install the ?CD3 moiety into broad functionalities including phenols, thiophenols, acidic amines, and enolizable methylene units in high yield and at a useful level of deuteration (>87% D).