1008419-96-2Relevant academic research and scientific papers
Selective functionalization of fullerenes with N,N-dihalosulfonamides as an N1 unit: Versatile syntheses of aza[60]fulleroids and aziridino[60]fullerenes and their application to photovoltaic cells
Nagamachi, Toshiki,Takeda, Youhei,Nakayama, Kazuhisa,Minakata, Satoshi
supporting information, p. 12035 - 12045 (2012/10/30)
Highly selective and versatile methods for the synthesis of aza[60]fulleroids and aziridino[60]fullerenes from C60 have been developed. The reactions utilized N,N-dihalosulfonamides as an N1 source. The photophysical, electrochemical
Aziridination of C60 with simple amides and catalytic rearrangement of the aziridinofullerenes to azafulleroids
Tsuruoka, Ryoji,Nagamachi, Toshiki,Murakami, Yuta,Komatsu, Mitsuo,Minakata, Satoshi
scheme or table, p. 1691 - 1697 (2009/07/30)
The selective formation of aziridinofullerene and azafulleroid, which are isomers of the fullerene derivatives-introduced N1 unit, is achieved. The ionic aziridination is a very convenient and risk-free procedure compared with the conventional
The ionic introduction of an N1 unit to C60 and a unique rearrangement of aziridinofullerene
Minakata, Satoshi,Tsuruoka, Ryoji,Nagamachi, Toshiki,Komatsu, Mitsuo
, p. 323 - 325 (2008/09/19)
A new chloramine-based aziridination of C60 and unique rearrangement of aziridinofullerene to azafulleroid is described. The ionic introduction of an N1 unit to C60via an addition-cyclization mechanism was first achieved under mild conditions; the combination of chloramine and MS4A resulted in the promising rearrangement of aziridinofullerene to azafulleroid, and the isomerization could be performed catalytically. The Royal Society of Chemistry.
