1008475-05-5Relevant academic research and scientific papers
Stereoselective synthesis of 3,4-disubstituted tetrahydrofurans and 2,3,4-trisubstituted tetrahydrofurans using an intramolecular allylation strategy employing allylsilanes
Jervis, Peter J.,Kariuki, Benson M.,Cox, Liam R.
, p. 2514 - 2518 (2008/09/19)
A Br?nsted acid-mediated intramolecular allylation involving an allylsilane and an aldehyde has been used as the key step in a stereoselective synthesis of 3,4-disubstituted tetrahydrofurans and 2,3,4-trisubstituted tetrahydrofurans.
A Bronsted acid mediated cascade enone synthesis from aldehydes containing a tethered propargylsilane
Ramalho, Rui,Jervis, Peter J.,Kariuki, Benson M.,Humphries, Alexander C.,Cox, Liam R.
, p. 1631 - 1634 (2008/09/17)
(Chemical Equation Presented) MeSO3H effects the intramolecular allenylation of a series of aldehydes 1 to provide allenyl alcohol product 3 as a single diastereoisomer. Cyclization proceeds rapidly at -78°C. However, when the reaction is perfo
