1008530-31-1Relevant academic research and scientific papers
Quantitatively correlating the effect of ligand-substituent size in asymmetric catalysis using linear free energy relationships
Miller, Jeremie J.,Sigman, Matthew S.
, p. 771 - 774 (2008/12/20)
Is bigger better? By systematically evaluating the size of the substituent G in a modular ligand (see picture), a linear free energy relationship was observed relating the product enantiomeric ratio to steric parameters developed by Charton. The reaction
