100868-34-6Relevant articles and documents
Novel ring transformation of nitropyrimidinone; synthetic equivalent of α-nitroformylacetic acid
Nishiwaki, Nagatoshi,Wang, Hui-Ping,Matsuo, Kengo,Tohda, Yasuo,Ariga, Masahiro
, p. 2261 - 2262 (2007/10/03)
3-Methyl-5-nitropyrimidin-4(3H)-one reacts with ketones in the presence of ammonium salts to afford disubstituted pyrimidines and disubstituted 3-nitro-2-pyridones in a novel ring transformation reaction; nitropyrimidinone behaves as an activated diformylamine in the former case, and as a synthetic equivalent of α-nitroformylacetic acid in the latter case.