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1008763-36-7

[MnCl((CH(C6H2(CH3)3)NCHC6H2(C6H2(CH3)3)2O)2)](1+) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1008763-36-7 Structure

  • Basic information

    1. Product Name: [MnCl((CH(C6H2(CH3)3)NCHC6H2(C6H2(CH3)3)2O)2)](1+)
    2. Synonyms:
    3. CAS NO:1008763-36-7
    4. Molecular Formula:
    5. Molecular Weight: 1065.76
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1008763-36-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [MnCl((CH(C6H2(CH3)3)NCHC6H2(C6H2(CH3)3)2O)2)](1+)(CAS DataBase Reference)
    10. NIST Chemistry Reference: [MnCl((CH(C6H2(CH3)3)NCHC6H2(C6H2(CH3)3)2O)2)](1+)(1008763-36-7)
    11. EPA Substance Registry System: [MnCl((CH(C6H2(CH3)3)NCHC6H2(C6H2(CH3)3)2O)2)](1+)(1008763-36-7)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1008763-36-7(Hazardous Substances Data)

1008763-36-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1008763-36-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,8,7,6 and 3 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1008763-36:
(9*1)+(8*0)+(7*0)+(6*8)+(5*7)+(4*6)+(3*3)+(2*3)+(1*6)=137
137 % 10 = 7
So 1008763-36-7 is a valid CAS Registry Number.

1008763-36-7Upstream product

1008763-36-7Downstream Products

1008763-36-7Relevant articles and documents

Transient intermediates from Mn(salen) with sterically hindered mesityl groups: Interconversion between MnIV-phenolate and Mn III-phenoxyl radicals as an origin for unique reactivity

Kurahashi, Takuya,Kikuchi, Akihiro,Tosha, Takehiko,Shiro, Yoshitsugu,Kitagawa, Teizo,Fujii, Hiroshi

, p. 1674 - 1686 (2008)

In order to reveal structure-reactivity relationships for the high catalytic activity of the epoxidation catalyst Mn(salen), transient intermediates are investigated. Steric hindrance incorporated to the salen ligand enables highly selective generation of three related intermediates, O=MnIV(salen), HO-MnIV(salen), and H2O-Mn III(salen+?), each of which is thoroughly characterized using various spectroscopic techniques including UV-vis, electron paramagnetic resonance, resonance Raman, electrospray ionization mass spectrometry, 2H NMR, and X-ray absorption spectroscopy. These intermediates are all one-electron oxidized from the starting Mn III(salen) precursor but differ only in the degree of protonation. However, structural and electronic features are strikingly different: The Mn-O bond length of HO-MnIV(salen) (1.83 A) is considerably longer than that of O=MnIV(salen) (1.58 A); the electronic configuration of H2O-MnIII(salen+?) is MnIII-phenoxyl radical, while those of O=MnIV(salen) and HO-MnIV(salen) are MnIV-phenolate. Among O=Mn IV(salen), HO-MnIV(salen), and H2O-Mn III(salen+?), only the O=MnIV(salen) can transfer oxygen to phosphine and sulfide substrates, as well as abstract hydrogen from weak C-H bonds, although the oxidizing power is not enough to epoxidize olefins. The high activity of Mn(salen) is a direct consequence of the favored formation of the reactive O=MnIV(salen) state.

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