1008776-27-9Relevant academic research and scientific papers
Enantioselective catalytic carbonyl-ene cyclization reactions
Grachan, Melissa L.,Tudge, Matthew T.,Jacobsen, Eric N.
, p. 1469 - 1472 (2008)
(Chemical Equation Presented) Intramolecular ene reactions of simple alkenyl aldehydes are catalyzed by a chiral (Schiff base)CrIII complex with high enantio-and diastereoselectivity, affording densely functionalized heterocyclic or carbocyclic products (see scheme for example). Desymmetrizations of alkenyl dialdehydes and bis(alkenyl) aldehydes are also achieved.
