100897-39-0

Basic information

• Product Name: RuH(SNC₅H₄)(CO)(P(C₆H₅)3)2
• CAS NO: 100897-39-0
• Molecular Weight: 764.83
• Mol File: 100897-39-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: RuH(SNC₅H₄)(CO)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: RuH(SNC₅H₄)(CO)(P(C₆H₅)3)2(100897-39-0)
• EPA Substance Registry System: RuH(SNC₅H₄)(CO)(P(C₆H₅)3)2(100897-39-0)

Safety Data

• Hazardous Substances Data: 100897-39-0(Hazardous Substances Data)

Upstream product

• 2637-34-5 2-Sulfanylpyridine 
• 25360-32-1 carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 2127-03-9 2,2'-dipyridyldisulphide 
• 16971-34-9 RuHBr(CO)[P(C₆H₅)3]3 
• 20332-49-4 tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾ 

Downstream Products

• 182116-89-8 Ru(H)(CO)(HSC₅H₄N)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=[Ru(H)(CO)(HSC₅H₄N)(P(C₆H₅)3)2]BF₄ 
• 182265-39-0 [Ru(η(2)-H2)(CO)(SC5H4N)(PPh3)2]BF4 
• 182265-39-0 [Ru(η(2)-H2)(CO)(SC5H4N)(PPh3)2]BF4 

Relevant articles and documents

Complexes of the Platinum Metals. Part 29. Pyridine-2-thiolate Derivatives of Ruthenium and Osmium: X-Ray Crystal Structures of and

Ruthenium and osmium precursors , , , , , and react with pyridine-2-thiol (pySH) or dipyridyl-2,2'-disulphide (pySSpy) in boiling benzene or toluene to afford a range of pyridin-2-thiolate complexes including , (2 isomers), , , and in which the pyridin-2-thiolate ligands are bound in monodentate (S-bonded) or bidentate (N,S-chelated) mode.Similar products are obtained from and in the presence of triethylamine and pyridine-2-thiol.The new complexes have been characterised by i.r. and n.m.r. (31P- and 1H) spectroscopy; reaction pathways are discussed.The X-ray crystal structures of and have been determined.The dicarbonyl , which undergoes facile conversion to , displays structural evidence of incipent attack by the non-co-ordinated N atom of the monodentate pyridine-2-thiolate ligand on a carbonyl group .Crystals of are monoclinic, space group P21/c, with a = 11.307(2), b = 11.083(3), c = 24.090(5) Angstroem, β = 109.47(2) deg, and Z = 4.The structure, which has been refined to R = 0.045 for 4375 observed reflections, consists of highly distorted octahedral ruthenium(II) molecules with monodentate (S-bonded) and bidentate (N,S-bonded) pyridine-2-thiolate ligands, a cis pair of carbonyl groups, and a triphenylphosphine ligand trans to the S-bonded pyridin-2-thiolate.Crystals of are triclinic, space group P1, with a = 10.317(3), b = 11.749(3), c = 12.517(3) Angstroem, α = 67.65(2), β = 70.55(2), γ = 86.43(2) deg, and Z = 2.The structure, which has been refined to R = 0.040 for 12196 observed reflections consists of highly distorted octahedral ruthenium(II) molecules with a cis pair of bidentate (N,S-bonded) pyridine-2-thiolate ligands (trans S atoms), a carbonyl group, and a triphenylphosphine ligand.