1009035-23-7

Basic information

• Product Name: 8-phenylphenanthridine
• Synonyms: 8-phenylphenanthridine
• CAS NO: 1009035-23-7
• Molecular Weight: 255.319
• Mol File: 1009035-23-7.mol

Chemical Properties

• CAS DataBase Reference: 8-phenylphenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 8-phenylphenanthridine(1009035-23-7)
• EPA Substance Registry System: 8-phenylphenanthridine(1009035-23-7)

Safety Data

• Hazardous Substances Data: 1009035-23-7(Hazardous Substances Data)

Upstream product

• 28322-50-1 2-diazo-1-phenyl-2-(phenylsulfonyl)ethan-1-one 
• 76129-23-2 [1,1':4',1''-terphenyl]-2-amine 
• 98-80-6 phenylboronic acid 
• 1009034-75-6 N-(2-ethynylphenyl)-N-prop-2-ynyl-acetamide 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Synthesis of phenanthridines through iodine-supported intramolecular C-H amination and oxidation under visible light

Herein, we report a metal-free and step-economic synthesis of phenanthridines from 2-biarylmethanamines under mild conditions. The reaction involves iodine-supported intramolecular C-H amination and oxidation of 5,6-dihydrophenanthridine under air and benign visible light. The mechanism study reveals that visible light plays a key role in both these steps.

Metal-free tandem carbene N-H insertions and C-C bond cleavages

A metal-free C-H [5 + 1] annulation reaction of 2-arylanilines with diazo compounds has been achieved, giving rise to two types of prevalent phenanthridines via highly selective C-C cleavage. Compared to the simple N-H insertion manipulation of diazo, this method elegantly accomplishes a tandem N-H insertion/SEAr/C-C cleavage/aromatization reaction, and the synthetic utility of this new transformation is exemplified by the succinct syntheses of trisphaeridine and bicolorine alkaloids. This journal is

PLATINUM COMPOUNDS, COMPOSITIONS AND METHODS FOR THE TREATMENT OF CANCER

The present disclosure relates to novel pharmaceutical compositions comprising a nanoparticle associated with, tether to, or encapsulating a platinum-based active pharmaceutical agent. The platinum-based drug is released from the nanoparticles in a controlled fashion. Also contemplated are methods of making the nanoparticles, as well as methods for using them in the treatment or prevention of diseases or conditions. One embodiment relates to phenanthriplatin nanoparticles and methods of using and making the same.

Phenanthridine synthesis via [2+2+2] cyclotrimerization reactions

A concise synthesis of phenanthridines via a microwave-assisted [2+2+2] cyclotrimerization reaction has been developed. This journal is The Royal Society of Chemistry.