1009306-05-1

Basic information

• Product Name: [PtBr(bis(dicyclohexylphosphino)ethane)(B(Br)(ferrocenyl))]
• CAS NO: 1009306-05-1
• Molecular Weight: 973.342
• Mol File: 1009306-05-1.mol

Chemical Properties

• CAS DataBase Reference: [PtBr(bis(dicyclohexylphosphino)ethane)(B(Br)(ferrocenyl))](CAS DataBase Reference)
• NIST Chemistry Reference: [PtBr(bis(dicyclohexylphosphino)ethane)(B(Br)(ferrocenyl))](1009306-05-1)
• EPA Substance Registry System: [PtBr(bis(dicyclohexylphosphino)ethane)(B(Br)(ferrocenyl))](1009306-05-1)

Safety Data

• Hazardous Substances Data: 1009306-05-1(Hazardous Substances Data)

Upstream product

• 23743-26-2 1,2-bis-(dicyclohexylphosphino)ethane 

Relevant articles and documents

Conversion of trans-bromoboryl platinum complexes into their cis-analogues upon treatment with chelating bisphosphines

Oxidative addition of B-halogen bonds to Pt(O) centers generally leads to corresponding trans-halo(boryl)complexes. Here, we report on a series of unprecedented ci-bromo(boryl)species of the type cw-[(dcpe)Pt{B(Br)R)(Br)], which were obtained from corresponding complexes trans-[(Cy3P)2Pt(B(Br)R)(Br)] (R = Fc, Pip, Mes) (Cy = cyclohexyl; Fc = ferroceny; Pip = piperidyl, Mes = mesityl) upon treatment with the chelating bisphosphine dcpe (=bis(dicyclohexyl)phosphinoethane). In CH 2Cl2 solution and in the presence of PCy3, one of these products, cw-[(dcpe)Pt{B(Br)Mes)(Br)], is converted into the corresponding chloroboryl complex cis-[(dcpe)Pt{B(Cl)Mes)(Br)]. All compounds were fully characterized by multinuclear NMR spectroscopy and single-crystal X-ray analyses.