1009332-10-8

Basic information

• Product Name: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)La(CH₂C₆H₅)2(OC₄H₈)
• CAS NO: 1009332-10-8
• Molecular Weight: 810.936
• Mol File: 1009332-10-8.mol

Chemical Properties

• CAS DataBase Reference: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)La(CH₂C₆H₅)2(OC₄H₈)(CAS DataBase Reference)
• NIST Chemistry Reference: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)La(CH₂C₆H₅)2(OC₄H₈)(1009332-10-8)
• EPA Substance Registry System: (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)La(CH₂C₆H₅)2(OC₄H₈)(1009332-10-8)

Safety Data

• Hazardous Substances Data: 1009332-10-8(Hazardous Substances Data)

Upstream product

• 2785-29-7 benzyl potassium 
• 1009332-07-3 (((CH₃)2CH)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2)LaBr₂(OC₄H₈)2 
• 905297-94-1 LaBn₃(tetrahydrofuran)₃ 
• 289618-59-3 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene 

Relevant articles and documents

Strategies for the synthesis of lanthanum dialkyl complexes with monoanionic ancillary ligands

The synthesis of lanthanum dialkyl complexes with monoanionic ancillary ligands [L]- is pursued by three different strategies: (a) in situ peralkylation of LaBr3(THF)4 with 3 equiv of LiCH 2SiMe3 followed by reaction with LH; (b) reaction of isolated La(CH2Ph)3(THF)3with LH; (c) stepwise salt metathesis on LaBr3(THF)4. Methods (a) and (b) generally work well for triazacyclononane-amide and amidinate ligands, but are unsuitable for the sterically demanding β-diketiminate [HC(MeC-NAr) 2]- (Ar = 2,6-iPr2C6H3) due to its high affinity for the Li cation and the sluggish reactivity of the diketimine. Nevertheless, the β-diketiminate lanthanum dibenzyl complex [HC(MeCNAr)2]-La(CH2Ph)2(THF) could be obtained by first reacting LaBr3(THF)4 with K[HC(MeCNAr) 2] to form [HC(MeCNAr)2]LaBr2(THF)2 and subsequent reaction of this dibromide complex with 2 equiv of PhCH 2K. When this reaction mixture is warmed, the product decomposes by H-abstraction from one of the diketiminate methyl groups and ligand redistribution, forming the coordination polymer {[μ-η2: η1-ArNC(Me)CHC(CH2)NAr]2La[K(THF) 4]}∞.