1009364-03-7Relevant academic research and scientific papers
Palladium-catalyzed silyl C(sp3)-H bond activation
Liang, Yun,Geng, Weizhi,Wei, Junnian,Ouyang, Kunbing,Xi, Zhenfeng
supporting information; experimental part, p. 1537 - 1542 (2012/03/22)
The first transition-metal-catalyzed activation of silyl C(sp 3)-H bond was realized and synthetically applied. A variety of organic skeletons substituted with SiMe3 groups could undergo the Pd-catalyzed intramolecular coupling react
Synthesis of stereo-defined 1,1,4,4-tetrahalo- and 1,1,4,4-mixed-tetrahalo-1,3-butadienes
Zhang, Hui-Jun,Song, Zhiyi,Wang, Chao,Bruneau, Christian,Xi, Zhenfeng
, p. 624 - 627 (2008/09/16)
Stereo-defined 1,1,4,4-tetrahalo- and 1,1,4,4-mixed-tetrahalo-1,3-butadienes were obtained in excellent yields via desilylation-halogenation of their corresponding 1,4-bis(trimethylsilyl)-1,4-dihalo-1,3-dienes, which could be readily prepared from the zir
