1009375-37-4Relevant academic research and scientific papers
A versatile synthesis of annulated carbazole analogs involving a domino reaction of bromomethylindoles with arenes/heteroarenes
Dhayalan, Vasudevan,Clement, J. Arul,Jagan, Radhakrishnan,Mohanakrishnan, Arasambattu K.
supporting information; experimental part, p. 531 - 546 (2009/09/06)
A ZnBr2-mediated arylation of aryl/heteroaryl methyl bromides with arenes at 80°C led to the formation of arylated products, which underwent subsequent 1,5-sigmatropic rearrangement followed by electrocyclization and aromatiza tion with loss of a diethylmalonate unit to afford the corresponding annulated products.
Synthesis of di-, tri-, and tetra-substituted carbazole analogs involving annulation methodology
Ramesh, Neelamegam,Rajeshwaran, Ganesan Gobi,Mohanakrishnan, Arasambattu K.
experimental part, p. 3592 - 3602 (2009/09/06)
Synthesis of substituted carbazole analogs was achieved via Michael addition followed by intramolecular cyclization and subsequent aromatization.
Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical
Ramesh, Neelamegam,Prakash, Chandran,Sureshbabu, Radhakrishnan,Dhayalan, Vasudevan,Mohanakrishnan, Arasambattu K.
, p. 2071 - 2079 (2008/09/17)
A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.
