100971-82-2Relevant articles and documents
Barbier-type reactions of nitriles and alkyl iodides mediated by samarium(II) iodide in the presence of catalytic nickel(II) iodide
Kang, Han-Young,Song, Sang-Eun
, p. 937 - 939 (2000)
The samarium(II) iodide-mediated intermolecular Barbier-type reactions of nitriles and alkyl iodides have been investigated. In the presence of a catalytic amount of nickel(II) iodide, the reaction proceeded smoothly to provide the corresponding ketones. Amides also reacted to give ketones under the same Barbier-type conditions. (C) 2000 Elsevier Science Ltd.
Ruthenium-catalyzed isomerization of homoallylic alcohols in water
Wang, Dong,Chen, Dongli,Haberman, John X.,Li, Chao-Jun
, p. 5129 - 5142 (2007/10/03)
Through the catalysis of RuCl2(PPh3)3, the functional groups of homoallylic alcohols are repositioned to give allylic alcohols with controlled regioselectivity. The reaction proceeds most efficiently in an aqueous media. The selectivity in product formation is affected by the reaction temperature and the amount of the catalyst being used. A higher reaction temperature and the use of a smaller amount of the catalyst are preferable for the formation of allylic alcohols. The reaction process was postulated as a tandem olefin migration-allylic rearrangement. Under the same reaction conditions, the functional groups of allylic alcohols undergo allylic rearrangements.
SYNTHESIS AND SPECTROSCOPY OF 1,4-DIALKYLBENZENES
Issac, Yvette A.,El-Zein, S. M.,Barakat, Y.
, p. 463 - 470 (2007/10/02)
Five linear 1,3-dialkylbenzenes namely, dibutyl-, dipentyl-, dihexyl-, diheptyl- and dioctylbenzenes were prepared in good yield via two simple catalytic routes under very mild conditions and affording insignificant side products, The starting feed, 1,4-d
Tetrathiafulvalenes. XXV. Conjugative Connected Polymeric Tetrathiafulvalenes (TTF)
Trinh, V.Q.,Hinh, L. van,Schukat, G.,Fanghaenel, E.
, p. 826 - 834 (2007/10/02)
Syntheses and properties of a conjugative connected polymeric TTF (by tetrahydroanthracene units) and phenylene-bridged polymeric TTF are described.These polymers react with bromine, iodine or tetracyanoquinodimethane and form the radical cation salts, wh