1009736-63-3Relevant academic research and scientific papers
Steric isotope effects gauged by the bowl-inversion barrier in selectively deuterated pentaarylcorannulenes
Hayama, Tomoharu,Baldridge, Kim K.,Wu, Yao-Ting,Linden, Anthony,Siegel, Jay S.
, p. 1583 - 1591 (2008/09/18)
Motivated by a greater bowl depth and barrier to bowl inversion in sym-1,3,5,7,9-pentamanisylcorannulene compared to corannulene, an experimental plan is developed to measure the effective hydrogen/deuterium steric kinetic isotope effect (KIE). Symmetry a
