1009809-26-0Relevant academic research and scientific papers
Palladium-catalyzed dienylations of chelated enolates
Basak, Sankar,Kazmaier, Uli
supporting information; experimental part, p. 4169 - 4177 (2009/05/30)
Isomerization-free reactions of dienyl carbonates with chelated amino acid ester enolates at -78 °C provide important information concerning the mechanism of these dienylations. The formation of regioisomeric products can be explained by competing SN2/SN2′ reactions, and the product distribution can be influenced by the proper choice of the reaction conditions. Chiral allylic substrates show a significant transfer of chirality. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
