100990-03-2Relevant academic research and scientific papers
GENERAL SYNTHESIS OF 2,5-DIHYDROTHIOPHENES (3-THIOLENES) FROM DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Hoshino, Masamatsu
, p. 1981 - 1982 (2007/10/02)
The intramolecular reductive coupling reaction of easily accesible diketo sulfides by a low-valent titanium reagent (prepared from titanium(IV) chloride and zinc powder) provides an efficient general synthesis of 2,5-dihydrothiophenes.
EFFICIENT PREPARATION OF POLYSUBSTITUTED 1,3-DIENES FROM α,α'-DIKETO SULFIDES
Nakayama, Juzo,Machida, Haruki,Saito, Ryuji,Akimoto, Keiichi,Hoshino, Masamatsu
, p. 1173 - 1176 (2007/10/02)
A series of polysubstituted 1,3-dienes were prepared in good overall yields in three steps starting from readily accessible α,α'-diketo sulfides.
