1010075-20-3

Basic information

• Product Name: trans-(1R,2R)-2-(phenylseleno)-1-cyclohexanol
• CAS NO: 1010075-20-3
• Molecular Weight: 255.218
• Mol File: 1010075-20-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: trans-(1R,2R)-2-(phenylseleno)-1-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: trans-(1R,2R)-2-(phenylseleno)-1-cyclohexanol(1010075-20-3)
• EPA Substance Registry System: trans-(1R,2R)-2-(phenylseleno)-1-cyclohexanol(1010075-20-3)

Safety Data

• Hazardous Substances Data: 1010075-20-3(Hazardous Substances Data)

Upstream product

• 286-20-4 cyclohexane-1,2-epoxide 
• 72726-46-6 tert-butyl(dimethyl)(phenylseleno)silane 
• 286-20-4 cyclohexene oxide 
• 645-96-5 Benzeneselenol 
• 50984-16-2 rac-2-(phenylseleno)cyclohexanone 

Relevant articles and documents

Enantioselective ring-opening reaction of meso-epoxides with ArSeH catalyzed by heterometallic Ti-Ga-Salen system

(Chemical Equation Presented) The first example of enantioselective ring-opening reaction of meso-epoxides with aryl selenols to give optically active β-arylseleno alcohol in up to 97% ee was realized, using a chiral Ti-Ga-Salen heterometallic catalyst. A strong synergistic effect of different Lewis acids in the system was exhibited in the catalytic process.

Synthesis of enantiomerically enriched β-hydroxy selenides by catalytic asymmetric ring opening of meso-epoxides with (phenylseleno)silanes

The first example of the enantioselective ring opening of meso-epoxides by (phenylseleno)silanes using salen(Cr)complexes as catalyst is described. This desymmetrization reaction constitutes a simple and convenient approach to synthetically versatile optically active β-hydroxy selenides.