101011-69-2

Basic information

• Product Name: [(Ph3P)4Ru2(μ-CF3SO2)(CO)2]HC(SO2CF3)2
• CAS NO: 101011-69-2
• Molecular Weight: 1721.57
• Mol File: 101011-69-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(Ph3P)4Ru2(μ-CF3SO2)(CO)2]HC(SO2CF3)2(CAS DataBase Reference)
• NIST Chemistry Reference: [(Ph3P)4Ru2(μ-CF3SO2)(CO)2]HC(SO2CF3)2(101011-69-2)
• EPA Substance Registry System: [(Ph3P)4Ru2(μ-CF3SO2)(CO)2]HC(SO2CF3)2(101011-69-2)

Safety Data

• Hazardous Substances Data: 101011-69-2(Hazardous Substances Data)

Upstream product

• 25360-32-1 carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 428-76-2 bis(perfluoromethylsulfonyl)methane 

Downstream Products

• 101011-71-6 [((C₆H₅)3P)2RuH(CO)(CH₃CN)2]⁽¹⁺⁾*[HC(SO₂CF₃)2]^(1-) = [((C₆H₅)3P)2RuH(CO)(CH₃CN)2]HC(SO₂CF₃)2 
• 101011-70-5 [((C₆H₅)3P)2RuH(CO)(CH₃CN)2]⁽¹⁺⁾*CF₃SO₂^(1-) = [((C₆H₅)3P)2RuH(CO)(CH₃CN)2]CF₃SO₂ 

Relevant articles and documents

Organometallic chemistry of fluorocarbon acids. Synthesis, structure, and solvolysis of a sulfinate-bridged diruthenium dihydride cluster, [(Ph3P)4Ru2(μ-H)2(μ-CF 3SO2)(CO)2]HC(SO2CF 3)2

Reaction of (Ph3P)3RuH2(CO) with 2 equiv of the fluorocarbon acids H2C(SO2CF3)2 or PhCH(SO2CF3)2 in toluene at >80°C produces the HC(SO2CF3)2- or PhC(SO2CF3)2- salts of (Ph3P)4Ru2(μ-H)2(μ-CF 3SO2)(CO)2+, in which the bridging hydrides were located by very high field 1H NMR. The bridging bidentate CF3SO2 group in [(Ph3P)4Ru2(μ-H)(μ-CF3SO 2)(CO)2]HC-(SO2CF3) 2·CH2Cl2 was established by single-crystal X-ray diffraction [P1 (triclinic), a = 16.300 (3) A?, b = 17.783 (4) A?, c = 14.496 (2) A?, α = 92.74 (1)°, β = 90.84 (1)°, γ = 111.82 (1)°, Z = 2]. This compound reacts with acetonitrile to form salts of (Ph3P)2RuH(CO)(CH3CN)2+. In the HC(SO2CF3)2- derivative [P21/n (monoclinic), a = 14.561 (3) A?, b = 16.858 (3) A?, c = 19.122 (4) A?, β = 93.55 (2)°, Z = 4], d(Ru-N, trans to CO) is 2.108 (5) A? while d(Ru-N, trans to H) is 2.163 (5) A? and one of the acetonitrile ligands rapidly exchanges with CD3CN.