101028-21-1

Basic information

• Product Name: (Z)-1,4-Dioxo-1-phenyl-2-pentene
• Synonyms: (Z)-1,4-Dioxo-1-phenyl-2-pentene
• CAS NO: 101028-21-1
• Molecular Weight: 174.199
• Mol File: 101028-21-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-1,4-Dioxo-1-phenyl-2-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1,4-Dioxo-1-phenyl-2-pentene(101028-21-1)
• EPA Substance Registry System: (Z)-1,4-Dioxo-1-phenyl-2-pentene(101028-21-1)

Safety Data

• Hazardous Substances Data: 101028-21-1(Hazardous Substances Data)

Upstream product

• 1074-12-0 phenylglyoxal hydrate 
• 4440-01-1 lithium phenylacetylide 
• 16330-23-7 1-phenyl-1-pentyn-4-ol 
• 2684-62-0 diazoacetone 
• 3282-32-4 2-diazo-acetophenone 
• 64-17-5 ethanol 
• 33651-05-7 trans-1-phenyl-2-pentene-1,4-dione 
• 1439-36-7 1-triphenylphosphoranylidene-2-propanone 

Downstream Products

• 101028-24-4 cis-2,3-epoxy-1-phenylpentane-1,4-dione 

Relevant articles and documents

A new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems

o-Iodoxybenzoic acid (IBX) was found to mediate the conversion of α-alkynyl alcohols into Z-enediones under notably mild conditions via a novel rearrangement mechanism (33-65% yield, 13 examples). The Royal Society of Chemistry 2006.

Selective oxyfunctionalization of (tricarbonylcyclohexadiene)iron-substituted furans with singlet oxygen and dimethyldioxirane

The versatility of the tricarbonyliron fragment as protecting group in the oxyfunctionalization of cyclohexadienyl-substituted furans with singlet oxygen (1O2), dimethyldioxirane (DMD) and m-chloroperoxybenzoic acid (mCPBA) was inves