101035-87-4Relevant academic research and scientific papers
The Synthesis of (E)-7-Methyl-tridec-6-en-1-ol: A Comparative Study on the Stereoselective Synthesis of (E)-Trisubstituted Double Bonds
Bernardi, Anna,Cabri, Walter,Poli, Giovanni,Prati, Laura
, p. 701 - 717 (2007/10/02)
Several routes to (E)-7-methyltridec-6-en-1-ol (2) have been carried out in order to present a useful comparative study on the stereoselective synthesis of (E)-trisubstituted double bonds.Di-n-pentyl-lithiumcuprate addition to four different allylic systems gave (2), after depyranylation, with E Z selectivities ranging from 3:1 to 40:1 depending on the nature and the position of the leaving group.
