1010398-69-2

Basic information

• Product Name: [W(η1,μ-CO-B(NMe2)-B(NMe2)-(η5-C5H4))(CO)2(Pt(PPh3)2)] (W-Pt)
• CAS NO: 1010398-69-2
• Molecular Weight: 1161.4
• Mol File: 1010398-69-2.mol

Chemical Properties

• CAS DataBase Reference: [W(η1,μ-CO-B(NMe2)-B(NMe2)-(η5-C5H4))(CO)2(Pt(PPh3)2)] (W-Pt)(CAS DataBase Reference)
• NIST Chemistry Reference: [W(η1,μ-CO-B(NMe2)-B(NMe2)-(η5-C5H4))(CO)2(Pt(PPh3)2)] (W-Pt)(1010398-69-2)
• EPA Substance Registry System: [W(η1,μ-CO-B(NMe2)-B(NMe2)-(η5-C5H4))(CO)2(Pt(PPh3)2)] (W-Pt)(1010398-69-2)

Safety Data

• Hazardous Substances Data: 1010398-69-2(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 1010398-65-8 Li[W(η5-C5H4Li)(CO)3] 
• 80476-71-7 1,2-dibromo-1,2-bis(dimethylamino)diborane 

Relevant articles and documents

Synthesis of a bimetallic platinum-tungsten complex with a bridging μ-diboranyl-oxycarbyne moiety

The novel bimetallic μ-diboranyl-oxycarbyne bridged platinum-tungsten complex [W{η1,μ-CO-B(NMe2)-B(NMe 2)-(η5-C5H4)}(CO) 2{Pt(PPh3)2}] (W-Pt) (3) has been synthesised by a two-step reaction, starting from the dilithiated half-sandwich compound Li[W(η5-C5H4Li)(CO)3] (1) via the ansa-diboranyl-oxycarbyne tungsten complex [W{η1-CO- B(NMe2)B(NMe2)(η5-C5H 4)}(OC)2] (2) by use of stoichiometric amounts of B 2(NMe2)2Br2 and [Pt(η 2-C2H4)(PPh3)2], respectively. The Royal Society of Chemistry.