101046-92-8Relevant articles and documents
A Stereoselective Synthesis of 1α-Hydroxyvitamin D3
Nemoto, Hideo,Kimura, Toshihiko,Kurobe, Hiroshi,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1777 - 1780 (2007/10/02)
A stereoslelective synthesis of 1α-hydroxyvitamin D3 (16) was achieved through the solvolysis of the 3,5-cyclovitamin D3 (14) which was prepared form (-)-(1R,3S,5S)-3-methoxymethoxy-2-methylenebicyclohexanecarbaldehyde (13) and 8-bromomethylenedes-AB-cholestane (1).