101049-86-9

Basic information

• Product Name: Mn⁽²⁺⁾*(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2)^(2-)=(Mn(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2))
• CAS NO: 101049-86-9
• Molecular Weight: 482.403
• Mol File: 101049-86-9.mol

Chemical Properties

• CAS DataBase Reference: Mn⁽²⁺⁾*(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2)^(2-)=(Mn(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2))(CAS DataBase Reference)
• NIST Chemistry Reference: Mn⁽²⁺⁾*(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2)^(2-)=(Mn(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2))(101049-86-9)
• EPA Substance Registry System: Mn⁽²⁺⁾*(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2)^(2-)=(Mn(NC₅H₃(CCH₃NNCOC₆H₄NH₂)2))(101049-86-9)

Safety Data

• Hazardous Substances Data: 101049-86-9(Hazardous Substances Data)

Upstream product

• 638-38-0 manganese(II) acetate 
• 85127-21-5 2,6-diacetylpyridinebis(2-aminobenzoic acid hydrazone) 

Relevant articles and documents

Versatility of 2,6-diacetylpyridine (dap) hydrazones in stabilizing uncommon coordination geometries of Mn(II): Synthesis, spectroscopic, magnetic and structural characterization

Five seven- or eight-coordinate manganese complexes of hydrazone ligands have been prepared. Three seven-coordinate neutral MnII complexes: [Mn(dapA2)]n (1), [Mn(dapB2)(H 2O)2] (2), [Mn(dap

Investigation into Aroylhydrazones as Chelating Agents. Part 7. Synthesis and Spectroscopic Characterization of Complexes of MnII, CoII, NiII, CuII, and ZnII with 2,6-Diacetylpyridine Bis(2-aminobenzoylhydrazone) and X-Ray Structure of Chloro<2,6-diacetylpyridine bis(2-amino...

A series of MnII, CoII, NiII, CuII, and ZnII complexes with 2,6-diacetylpyridine bis(2-aminobenzoylhydrazone) (H2dapab) has been prepared from the reaction of the hydrazone with metal chlorides and acetates.The i.r. spectra are reported and evaluated to obtain information on the co-ordinating behaviour of the hydrazone.An X-ray diffraction analysis carried out on Cl*H2O has shown it to possess pentagonal-bipyramidal geometry with the H2dapab ligand occupying the equatorial plane and the Cl and CH3OH groups at the axial sites.The structure has been refined to R=0.0676 for 2173 observed diffractometer data.