1010804-01-9Relevant articles and documents
Total syntheses of clausamines A-C and clausevatine D
Lebold, Terry P.,Kerr, Michael A.
supporting information; experimental part, p. 997 - 1000 (2009/04/07)
The first total syntheses of clausamines A-C and clausevatine D are reported. The key step involves a Diels-Alder reaction between an imine quinone and cyclic diene, allowing for the subsequent construction of the carbazole core in a regiospecific manner. Stereochemistry of the natural products is also discussed.