1010806-21-9

Upstream product

• 1010806-13-9 C₆₈HF₅O₂ 
• 100-51-6 benzyl alcohol 
• 187482-06-0 3'H-cyclopropa[1,9][5,6]fullereno-C₆₀-I_h-3'-carboxylic acid N-hydroxysuccinimide ester 
• 52267-51-3 benzyl diazoacetate 
• 99685-96-8 fullerene-C₆₀ 

Relevant academic research and scientific papers

Synthesis of fullerene C60monoadducts. Cyclopropanation of C60with sulfonium ylides

3′H-Cyclopropa[1,9](C60-Ih)[5,6]fullerene-3′-carboxylic acid can be synthesized in a good yield by cyclopropanation of fullerene C60with 2-(dimethyl-λ4-sulfanylidene)acetates provided that the ester residue is readily hydrolyzable in acid medium.

Cycloaddition of diazoacetates to C60 fullerene catalysed by Pd complexes

An efficient catalytic method of the cycloaddition to C60 fullerene of the diazoacetates, containing substituents of diverse structures in ester groups, in the presence of a Pd-based three-component catalyst was developed. An influence of nature and the structure of substituent in the ester group on the activity of diazoacetates in the reaction with C60 was studied. Yields of respective cycloadducts were determined.

Preparation of C60-based active esters and coupling of C60 moiety to amines or alcohols

We report the syntheses of C60-based active esters and the coupling of their C60 moiety to various amines or alcohols. Methano[60]fullerene carboxylic acid was activated by esterification with N-hydroxysuccinimide (NHS) or pentafluor