1011269-20-7

Basic information

• Product Name: (3,3-dimethyl-but-1-ynyl)-phenyl-carbamic acid tert-butyl ester
• Synonyms: (3,3-dimethyl-but-1-ynyl)-phenyl-carbamic acid tert-butyl ester
• CAS NO: 1011269-20-7
• Molecular Weight: 273.375
• Mol File: 1011269-20-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3,3-dimethyl-but-1-ynyl)-phenyl-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3,3-dimethyl-but-1-ynyl)-phenyl-carbamic acid tert-butyl ester(1011269-20-7)
• EPA Substance Registry System: (3,3-dimethyl-but-1-ynyl)-phenyl-carbamic acid tert-butyl ester(1011269-20-7)

Safety Data

• Hazardous Substances Data: 1011269-20-7(Hazardous Substances Data)

Upstream product

• 3422-01-3 tert-butyl phenylcarbamate 
• 13601-86-0 1-bromo-3,3-dimethyl-1-butyne 
• 24424-99-5 di-tert-butyl dicarbonate 
• 62-53-3 aniline 
• 917-92-0 3,3-Dimethylbut-1-yne 

Downstream Products

• 1011269-37-6 5-tert-butyl-3-phenyl-3H-oxazol-2-one 

Relevant articles and documents

Iridium-Catalyzed Highly Regioselective Azide-Ynamide Cycloaddition to Access 5-Amido Fully Substituted 1,2,3-Triazoles under Mild, Air, Aqueous, and Bioorthogonal Conditions

A highly regioselective method to access 5-amido fully substituted 1,2,3-triazoles by iridium-catalyzed azide-ynamide cycloaddition under mild, air, aqueous, and bioorthogonal conditions is reported. The excellent regioselectivities may derive from the strong coordination between the carbonyl oxygen of ynamide and the -acidic iridium. Since the iridium ion is insensitive to oxygen/water and exhibits low cytotoxicity, it could catalyze this reaction in both organic and biological environments efficiently. Preparation in gram-scale and application in carbohydrates highlight this method.