1011465-22-7

Basic information

• Product Name: R-3,3'-di-9-phenanthrenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-Binaphthalene]-2,2'-diol
• Synonyms: R-3,3'-di-9-phenanthrenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-Binaphthalene]-2,2'-diol;(1R)-5,5',6,6',7,7',8,8'-Octahydro-3,3'-di-9-phenanthrenyl- [1,1'-binaphthalene]-2,2'-diol;(R)-5,5',6,6',7,7',8,8'-Octahydro-3,3'-di-9-phenanthrenyl- [1,1'-binaphthalene]-2,2'-diol,99%e.e.;(R)-5,5',6,6',7,7',8,8'-Octahydro-3,3'-di-9-phenanthrenyl-[1,1'-binaphthalene]-2,2'-diol
• CAS NO: 1011465-22-7
• Molecular Formula: C48H38O2
• Molecular Weight: 646.81
• Mol File: 1011465-22-7.mol
• Article Data: 4

Chemical Properties

• Melting Point: 193-195 °C
• Appearance: /
• Density: 1.262±0.06 g/cm3(Predicted)
• PKA: 9.19±0.20(Predicted)
• CAS DataBase Reference: R-3,3'-di-9-phenanthrenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-Binaphthalene]-2,2'-diol(CAS DataBase Reference)
• NIST Chemistry Reference: R-3,3'-di-9-phenanthrenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-Binaphthalene]-2,2'-diol(1011465-22-7)
• EPA Substance Registry System: R-3,3'-di-9-phenanthrenyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-Binaphthalene]-2,2'-diol(1011465-22-7)

Safety Data

• Hazardous Substances Data: 1011465-22-7(Hazardous Substances Data)

Upstream product

• 68572-87-2 9-phenanthrenylboronic acid 

Downstream Products

• 1028416-47-8 9-phenanthrenyl 

Relevant articles and documents

Thieme chemistry journal awardees - Where are they now? Asymmetric br?nsted acid catalyzed transfer hydrogenations

Asymmetric hydrogenations are of great importance in the synthesis of optically active amines. This account highlights the development of the first metal-free transfer hydrogenation that is both highly enantioselective and inspired by natures dehydrogen?ase. Further focus is given to the extension of this bioinspired process to provide a variety of valuable, biologically active products and natural products under mild reaction conditions. Georg Thieme Verlag Stuttgart - New York.

Synthesis of BINOL derived phosphorodithioic acids as new chiral Br?nsted acids and an improved synthesis of 3,3′-disubstituted H8-BINOL derivatives

Original phosphorodithioic acid diesters were prepared according to an improved synthesis of 3,3′-disubstituted H8-BINOL derivatives. In preliminary experiments, these new Br?nsted acids were tested as organocatalysts in three reactions. They promoted the Nazarov cyclisation with mixed selectivities, the Mannich reaction with good enantioselectivity and they catalyzed efficiently the alkylation of N-acyliminium with enol silyl ether.