101155-78-6

Basic information

• Product Name: methyl 2-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside
• Synonyms: methyl 2-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside
• CAS NO: 101155-78-6
• Molecular Weight: 346.425
• Mol File: 101155-78-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside(101155-78-6)
• EPA Substance Registry System: methyl 2-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside(101155-78-6)

Safety Data

• Hazardous Substances Data: 101155-78-6(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 101155-77-5 methyl 2,3-di-O-p-toluenesulfonyl-4-O-benzoyl-6-S-acetyl-6-thio-α-D-glucopyranoside 
• 101155-76-4 methyl 2,3-di-O-p-toluenesulfonyl-4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside 
• 10368-81-7 methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside 

Downstream Products

• 101155-79-7 methyl 2,3-di-O-p-toluenesulfonyl-4,6-thioanhydro-α-D-gulopyranoside 
• 101155-80-0 Toluene-4-sulfonic acid (1R,3S,4R,5S,6R)-5-hydroxy-3-methoxy-7,7-dioxo-2-oxa-7λ⁶-thia-bicyclo[4.2.0]oct-4-yl ester 
• 101155-81-1 methyl 2-O-p-toluenesulfonyl-4,6-dideoxy-α-D-ribo-hexopyranoside 

Relevant articles and documents

4,6-THIOANHYDRO-HEXOPYRANOSIDES. SYNTHESIS AND CHEMICAL BEHAVIOUR OF METHYL 2-O-p-TOLUENESULFONYL-4,6-THIOANHYDRO-α-D-GULOPYRANOSIDE

Methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside (1, Figure 1) was converted, via the corresponding ditosylate 2, into methyl 2,3-di-O-p-toluenesulfonyl-4-O-benzoyl-6-S-acetyl-6-thio-α-D-glucopyranoside (3) by a selective nucleophilic displacement o