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1012050-42-8

(μ-pyrazine)bis[[2,6-bis[1-(2,4,6-trimethylphenylinino)ethyl]pyridine]tetrachlorodiruthenium(II)] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1012050-42-8 Structure

  • Basic information

    1. Product Name: (μ-pyrazine)bis[[2,6-bis[1-(2,4,6-trimethylphenylinino)ethyl]pyridine]tetrachlorodiruthenium(II)]
    2. Synonyms:
    3. CAS NO:1012050-42-8
    4. Molecular Formula:
    5. Molecular Weight: 1219.17
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1012050-42-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (μ-pyrazine)bis[[2,6-bis[1-(2,4,6-trimethylphenylinino)ethyl]pyridine]tetrachlorodiruthenium(II)](CAS DataBase Reference)
    10. NIST Chemistry Reference: (μ-pyrazine)bis[[2,6-bis[1-(2,4,6-trimethylphenylinino)ethyl]pyridine]tetrachlorodiruthenium(II)](1012050-42-8)
    11. EPA Substance Registry System: (μ-pyrazine)bis[[2,6-bis[1-(2,4,6-trimethylphenylinino)ethyl]pyridine]tetrachlorodiruthenium(II)](1012050-42-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1012050-42-8(Hazardous Substances Data)

1012050-42-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1012050-42-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,1,2,0,5 and 0 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1012050-42:
(9*1)+(8*0)+(7*1)+(6*2)+(5*0)+(4*5)+(3*0)+(2*4)+(1*2)=58
58 % 10 = 8
So 1012050-42-8 is a valid CAS Registry Number.

1012050-42-8Downstream Products

1012050-42-8Relevant articles and documents

Thermal study of ruthenium(II) complexes containing pyridine-2,6-diimines

Dogan,Dayan,Yuerekli,Cetinkaya

, p. 943 - 949 (2009/01/31)

Thermal behaviors of mono-and binuclear Ru(II)-pydim complexes: [PydimCl2RuL] (Pydim: pyridine-2,6-diimine; 2: L=NCMe; 3: L=PPh 3) and [PydimCl2Ru(L-L)RuCl2Pydim] (4: L-L=pyrazine; 5: L-L=4,4'-bipyridine) have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The decompositions of complexes occur in stepwise. The values of activation energy, E a, and reaction order, n of the thermal decomposition were calculated by means of several methods such as Coats-Redfern (CR), MacCallum-Tanner (MT), Horowitz-Metzger (HM), van Krevelen (vK), Madhusudanan-Krishnan-Ninan (MKN) and Wanjun-Yuwen-Hen-Cunxin (WYHC) based on the single heating rate. Most appropriate method was determined for each decomposition step according to the least-squares linear regression.

Mono- and binuclear ruthenium(II) complexes containing pyridine-2,6-diimine (Pydim) ligands: Synthesis, characterization and catalytic activity in the transfer hydrogenation of acetophenone

Dayan, Osman,?etinkaya, Bekir

, p. 134 - 141 (2008/10/09)

A series of neutral mono- and binuclear Ru(II) complexes: [PydimCl2RuL] (Pydim (1) pyridine-2,6-diimine; (2) L = NCMe; (3) L = PPh3) and [PydimCl2Ru(L-L)RuCl2Pydim] (4) L-L = pyrazine; (5) L-L = 4,4′-bipyridine) have been synthesized from the corresponding (p-cymene)ruthenium dichloride dimer, pydim and ancillary ligands L and L-L, respectively. The Pydim-Ru(II) complexes have been employed as catalysts for the transfer hydrogenation of acetophenone in the presence of KOH using 2-propanol as a hydrogen source. Ligand substitution studies indicate that there is a significant difference in reactivity between complexes containing L/L-L and Pydim. Yields of up to 93% were obtained after 5 min at 82 °C.

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