101231-96-3Relevant academic research and scientific papers
Biosynthesis of Porphyrins and Related Macrocycles. Part 30. Synthesis of the Macrocycle of the Spiro System Proposed as an Intermediate Generated by Cosynthetase
Stark, W. Marshall,Baker, G. Mark,Leeper, J. Finian,Raihby, R. Paul,Battersby, R. Alan
, p. 1187 - 1202 (2007/10/02)
Synthesis are described of two compounds having the 1,14-(propane-1,3-diyl)tripyrrin macrocycle (5), which is the basis of the spiro compound (2) proposed as an intermediate during the cyclization of hydroxy methylbilane (1) to uro'gen III (3), catalysed
The Spiro Intermediate Proposed for Biosynthesis of the Natural Porphyrins: Synthesis and Properties of Its Macrocycle
Stark, W. Marshall,Baker, Mark G.,Raithby, Paul R.,Leeper, Finian J.,Battersby, Alan R.
, p. 1294 - 1296 (2007/10/02)
Two structures have been synthesised containing the novel macrocycle on which is based the hypothetical spiro-intermediate for biosynthesis of the natural porphyrins; the strongly puckered conformation of the macrocycle is shown by X-ray structure analysi
