101246-52-0

Basic information

• Product Name: 5-phenyl-1,4,6,5-oxadithiabismocane
• CAS NO: 101246-52-0
• Molecular Weight: 422.325
• Mol File: 101246-52-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-phenyl-1,4,6,5-oxadithiabismocane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenyl-1,4,6,5-oxadithiabismocane(101246-52-0)
• EPA Substance Registry System: 5-phenyl-1,4,6,5-oxadithiabismocane(101246-52-0)

Safety Data

• Hazardous Substances Data: 101246-52-0(Hazardous Substances Data)

Upstream product

• 39110-02-6 dibromophenylbismuthane 
• 2150-02-9 bis(2-mercaptoethyl)ether 

Relevant articles and documents

UEBER BISMUT-HALTIGE HETEROCYCLEN I. METHYLIERTE UND PHENYLIERTE BISMOCANE, INTRA- UND INTERMOLEKULARE KOORDINATIONSERHOEHUNG AN BISMUT(III)

Methyl and phenyl oxadithia and trithiabismocanes have been synthesized from methyl or phenyl diethoxybismutane and the respective dithiol.The light-sensitive compounds have been investigated by mass, vibrational and 13C NMR spectra: ν(Bi-Me) 470-460, ν(BiS2) 300-240 cm-1; δ(13Me) -12ppm.The crystal structure of 5-phenyl-1,4,6,5-oxadithiabismocane has been determined (R = 0.056).The eight-membered ring has the chair-chair conformation.Besides three direct bonds (Bi-Ph 225(2), Bi-S 256.0(2) and 260.2(3) pm) there are one transannular (Bi...O 297(1) and two intermolecular contacts (Bi...S 344.0(3) and 350.9(3) pm) to bismuth in resulting a φ-monocapped octahedral sphere of coordination.These polyhedra are connected in sharing two different edges, and the crystal structure exhibits double chains of molecules.