101273-58-9Relevant articles and documents
Selectivity of N-versus O-alkylation in Mitsunobu reactions with various quinolinols and isoquinolinols
Hartung, Ryan E.,Wall, Mark C.,Lebreton, Sylvain,Smrcina, Martin,Patek, Marcel
, p. 1305 - 1313 (2017/07/18)
Reacting quinolinols and isoquinolinols under Mitsunobu conditions can give rise to N-alkylated products in addition to the normally desired O-alkylated structures. An in-depth study of how the solvent, reagent equivalents, position of the quinoline/isoqu
Tetrabutyl ammonium bromide-mediated benzylation of phenols in water under mild condition
Wang, Hailei,Ma, Yuping,Tian, Heng,Yu, Ajuan,Chang, Junbiao,Wu, Yangjie
, p. 2669 - 2673 (2014/04/03)
Benzylation of phenol was successfully achieved in water under room temperature mediated by tetrabutylammonium bromide (TBAB) for only 2 h affording the corresponding benzyl phenyl ether with good to excellent yields. This protocol is very efficient, simple, avoiding catalysts, easy to work-up after reaction, and especially 'green'.
An efficient approach towards syntheses of ethers and esters using CsF-Celite as a solid base
Shah, Syed Tasadaque A,Khan, Khalid M,Heinrich, Angelica M,Choudhary, M.Iqbal,Voelter
, p. 8603 - 8606 (2007/10/03)
The coupling reactions of a number of alcohols and phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite are described. It has been found that CsF-Celite combinations provide an efficient, convenient and practical method for syntheses of both, ethers and esters.
