10137-69-6 Usage
Chemical Properties
Different sources of media describe the Chemical Properties of 10137-69-6 differently. You can refer to the following data:
1. colourless fuming liquid
2. Cyclohexenyl trichlorosilane is a colorless
fuming liquid. Odor like hydrogen chloride.
General Description
A colorless liquid with a pungent odor. Flash point of 199°F. Corrosive to metals and tissue. Used to make various silicon containing compounds.
Air & Water Reactions
Reacts violently with water, steam, moist air, alcohols, acetone, light metals with generation of heat and combustible (H2) and corrosive (HCl) gases. on contact with air 3-CYCLOHEXENYLTRICHLOROSILANE gives off HCl gas. REF [Handling Chemicals Safely, 1980 p. 924].
Reactivity Profile
Chlorosilanes, such as 3-CYCLOHEXENYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. Special Hazards of Combustion Products: Irritating, toxic hydrogen chloride and phosgene may be generated in a fire.
Health Hazard
Inhalation causes irritation of mucous membrane. Contact with eyes or skin causes severe burns. Ingestion causes severe burns of mouth and stomach.
Safety Profile
Moderately toxic by
ingestion and skin contact. An eye and
severe skin irritant. A corrosive material. It
fumes in moist air, releasing HCl.
Combustible when exposed to heat or
flame. When heated to decomposition itemits toxic fumes of Cl-. See also
CHLOROSILANES.
Potential Exposure
This material is used to make silicone
polymers.
Shipping
UN1762 Cyclohexenyl trichlorosilane, Hazard
class: 8; Labels: 8-Corrosive material.
Incompatibilities
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explo-
sions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. Chlorosilanes react vigor-
ously with bases and both organic and inorganic acids gen-
erating toxic and/or flammable gases. Chlorosilanes react
with water, moist air, or steam releasing heat and toxic,
corrosive fumes of hydrogen chloride. The reaction may
also release flammable hydrogen fumes. Attacks metals in
the presence of moisture. Some chlorosilanes are pyro-
phoric; self-ignite in air. Contact with ammonia can cause
a self-igniting compound.
Check Digit Verification of cas no
The CAS Registry Mumber 10137-69-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,1,3 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10137-69:
(7*1)+(6*0)+(5*1)+(4*3)+(3*7)+(2*6)+(1*9)=66
66 % 10 = 6
So 10137-69-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H9Cl3Si/c7-10(8,9)6-4-2-1-3-5-6/h1-2,6H,3-5H2
10137-69-6Relevant articles and documents
Cyclohexadien-2,4-ylsilane and its derivatives, synthesis of the same, and the pyrolysis of the same to silane
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Page/Page column 5, (2008/06/13)
Silane gas precursor compounds having the formula (I): wherein R1, R2, and R3 each can independently be hydrogen or halogen and wherein the cyclohexadiene ring can have one or more substituents selected from the group consisting of a saturated or unsaturated, straight chain or branched alkyl group, a halogen, NO2, and C≡N are disclosed. In one form, the silane gas precursor compound is cyclohexadien-2,4-ylsilane, an air-stable liquid, that can be thermolyzed in a pyrolysis process to efficiently generate high purity silane gas. The compounds of the present invention can thus serve as a “point-of-use” precursor for silane gas.
