1014-69-3

Basic information

• Product Name: DESMETRYN
• Synonyms: 2-Isopropylamino-4-methylamino-6-methylthio-1,3,5-triazine;2-isopropylamino-4-methyl-amino-6-methylthio-s-triazine;2-Methylamino-4-methylthio-6-isopropylamino-1,3,5-triazine;2-methylmercapto-4-methylamino-6-isopropylamino-s-triazine;2-methylthio-3-methylamino-6-isopropylamino-1,3,5-triazine;2-Methylthio-4-isopropylamino-6-methylamino-s-triazine;5-triazine-2,4-diamine,n-methyl-n’-(1-methylethyl)-6-(methylthio)-3;caswellnumber509b
• CAS NO: 1014-69-3
• Molecular Formula: C₈H₁₅N₅S
• Molecular Weight: 213.3
• EINECS: 213-800-1
• Product Categories: Alpha sort;D;DA - DHPesticides&Metabolites;DAlphabetic;Herbicides;Pesticides&Metabolites;Triazines
• Mol File: 1014-69-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 85°C
• Boiling Point: 345°C (rough estimate)
• Flash Point: 11 °C
• Appearance: /
• Density: 1.1553 (rough estimate)
• Vapor Pressure: 3.75E-06mmHg at 25°C
• Refractive Index: 1.5500 (estimate)
• Storage Temp.: APPROX 4°C
• PKA: 3.66±0.41(Predicted)
• Water Solubility: 0.6g/L(20 oC)
• BRN: 612017
• CAS DataBase Reference: DESMETRYN(CAS DataBase Reference)
• NIST Chemistry Reference: DESMETRYN(1014-69-3)
• EPA Substance Registry System: DESMETRYN(1014-69-3)

Safety Data

• Hazard Codes: Xn,N,T,F
• Statements: 21/22-50/53-39/23/24/25-23/24/25-11
• Safety Statements: 36/37-60-61-45-16-7
• RIDADR: UN1230 3/PG 2
• WGK Germany: 3
• RTECS: XZ0175000
• Hazardous Substances Data: 1014-69-3(Hazardous Substances Data)

Usage

Uses

Desmetryn is used as an herbicide in the treatment of crops and vegetables. It is used to control specifically white goosefoot, as well as other weeds and grasses.

InChI:InChI=1/C8H15N5S/c1-5(2)10-7-11-6(9-3)12-8(13-7)14-4/h5H,1-4H3,(H2,9,10,11,12,13)

Upstream product

• 3004-71-5 6-chloro-N²-isopropyl-N⁴-methyl-1,3,5-triazine-2,4-diamine 
• 616-38-6 carbonic acid dimethyl ester 

Relevant articles and documents

Palladium-Catalyzed Thiomethylation via a Three-Component Cross-Coupling Strategy

In this report, the combination of masked inorganic sulfur and dimethyl carbonate was designed to achieve thiomethylated cross coupling of aryl chlorides. Remarkably, this powerful strategy realized thiomethylation of nucleosides bearing unprotected ribose, chloride-containing pharmaceuticals with late-stage coupling, and herbicides possessing multiple heteroatoms and steric hindrance. Moreover, this protocol is practically amenable to multigram-scale synthesis with a lower catalysis loading and a higher yield.

Plant-protective and pest-control agent

A herbicidal composition capable of preventing weed growth of potatoes or soybean plants consists of a triazene or an aromatic nitro compound together with an inorganic salt, especially sodium bisulfate or potassium bisulfate which reduced the quantity of the organic herbicide below that usually required to obtain a corresponding herbicidal effect and hence prevents phytotoxic damage. The composition contains 0.1:1 to 15:1 parts by weight of the inorganic compound to the organic compound and is applied in an amount of 0.1 to 30 kg of the composition per hectare.