101413-94-9

Basic information

• Product Name: 1-((Z)-1,2-Dichloro-propenylsulfanyl)-4-methyl-benzene
• Synonyms: 1-((Z)-1,2-Dichloro-propenylsulfanyl)-4-methyl-benzene
• CAS NO: 101413-94-9
• Molecular Weight: 233.161
• Mol File: 101413-94-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-((Z)-1,2-Dichloro-propenylsulfanyl)-4-methyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((Z)-1,2-Dichloro-propenylsulfanyl)-4-methyl-benzene(101413-94-9)
• EPA Substance Registry System: 1-((Z)-1,2-Dichloro-propenylsulfanyl)-4-methyl-benzene(101413-94-9)

Safety Data

• Hazardous Substances Data: 101413-94-9(Hazardous Substances Data)

Upstream product

• 21400-25-9 1,1,2-trichloropropene 
• 106-45-6 para-thiocresol 
• 103-19-5 di(p-tolyl) disulfide 

Relevant articles and documents

FREE-RADICAL REACTIONS OF 1,1,2-TRICHLOROPROPENE. II. FREE-RADICAL THIYLATION OF TRICHLOROPROPENE BY ARENETHIOLS

The reaction of CCl2=CClCH3 with ArSH (Ar = 4-ClC6H4, C6H4, 4-CH3C6H4), initiated by UV irradiation, is nonregioselective and nonstereospecific and leads mainly to the formation of mixtures of isomeric sulfides ArSC(CH3)=CCl2 and cis- and trans-ArSCCl=CClCH3.Diaryl disulfides ArSSAr, sulfides ArSCH2CCl=CCl2 and ArSCHClCCl2CH3, and bissulfides cis- and trans-ArSC(CH3)=CClSAr and (ArS)2=CClCH3 are also formed.In the case of 4-ClC6H4SH the thioester ClC6H4SC(O)CCl2CH3 was found.The formation of these products was demonstrated by GLC, IR and PMR spectroscopy, and chromato-mass spectrometry.A reaction mechanism involving the formation of intermediate radicals of ArSC(CH3)ClC.Cl2 and ArSCCl2C.ClCH3 and also the allyl radical .CH2CCl=CCl2 is proposed.