101434-25-7Relevant articles and documents
Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes
Yang, Ji,Liu, Jiawang,Neumann, Helfried,Franke, Robert,Jackstell, Ralf,Beller, Matthias
, p. 1514 - 1517 (2019)
The direct carbonylation of 1,3-butadiene offers the potential for a more cost-efficient and environmentally benign route to industrially important adipic acid derivatives. However, owing to the complex reaction network of regioisomeric carbonylation and isomerization pathways, a selective practical catalyst for this process has thus far proven elusive. Here, we report the design of a pyridyl-substituted bidentate phosphine ligand (HeMaRaphos) that, upon coordination to palladium, catalyzes adipate diester formation from 1,3-butadiene, carbon monoxide, and butanol with 97% selectivity and 100% atom-economy under industrially viable and scalable conditions (turnover number > 60,000). This catalyst system also affords access to a variety of other di- and triesters from 1,2- and 1,3-dienes.
SYNTHESIS OF ALIPHATIC POLYCARBOXYLIC ACID
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Page/Page column 10, (2016/03/22)
The present invention provides a method for synthesizing an aliphatic polycarboxylic acid, the method comprising the steps of: (a) dehydrating a polyhydroxycarboxlic acid using a rhenium-based catalyst to produce an unsaturated polycarboxylic acid precursor; and (b) performing a hydrogenation reaction on the unsaturated polycarboxylic acid precursor to produce the aliphatic polycarboxylic acid.
Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration
Li, Xiukai,Wu, Di,Lu, Ting,Yi, Guangshun,Su, Haibin,Zhang, Yugen
supporting information, p. 4200 - 4204 (2014/05/06)
The production of bulk chemicals and fuels from renewable bio-based feedstocks is of significant importance for the sustainability of human society. Adipic acid, as one of the most-demanded drop-in chemicals from a bioresource, is used primarily for the large-volume production of nylon-6,6 polyamide. It is highly desirable to develop sustainable and environmentally friendly processes for the production of adipic acid from renewable feedstocks. However, currently there is no suitable bio-adipic acid synthesis process. Demonstrated herein is the highly efficient synthetic protocol for the conversion of mucic acid into adipic acid through the oxorhenium-complex-catalyzed deoxydehydration (DODH) reaction and subsequent Pt/C-catalyzed transfer hydrogenation. Quantitative yields (99 %) were achieved for the conversion of mucic acid into muconic acid and adipic acid either in separate sequences or in a one-step process. Taking a dip: A highly efficient synthetic protocol has been developed for the conversion of mucic acid into adipic acid by the oxorhenium-complex-catalyzed deoxydehydration reaction and subsequent Pt/C-catalyzed transfer hydrogenation. Quantitative yields were achieved for the conversion of mucic acid into muconic acid and adipic acid esters either through separate sequences or through a one-pot process.